I have used 4A in the snow, and it's great.
one comment above i just wanted to clarify after doing much research myself, and differences between AWD and 4A. The truck doesnt have a center diff, it has a variable transfer case. in the case of a diff, 100% of torque can be directed in either direction. with the transfer case, as the drive shaft goes through the transfer case to the rear axle, you can never disengage the rear, and can only really go up to 50/50. But it's a electronically controlled wet clutch which can transfer 0-50 to the front, and basically lock up the clutch to get a 'locked' status.
So the problem with AWD vehicles and snow, (depending on tech, and vehicle computer applying brakes to various wheels), in a purely mechanical sense, you can have one wheel of the four without traction, and all torque applied to that wheel. This problem is compensated for by the computer applying brakes to slipping wheels.
back to the truck. so because it's a transfer case, rear is always getting torque. in 4A, the computer will decide if front wheels also get torque. but unless locked up, the transfer case allows slippage, so you dont get binding in corners.
The limited slip rear diff will intelligently only allow one wheel to slip before transferring torque to the other. (and can be locked up all together with the button)
The front diff doesn't have the locking option, but traction control will do what ADW vehicles do, and apply brakes to wheels which are loosing traction, transferring torque to the other side.
All together, the 4A mode by itself will do a very good job in snow.
if you are stuck, sure, you can lock the rear, which will help, but shouldn't be used on dry pavement due to binding.
Shane_th_ee also correctly mentioned the drive modes. when you put it in snow mode, i believe that basically puts it in 4H (locked transfer case), but again cautions on using this on dry pavement.
99.9% of the time, 4A, and proper snow tiers.