Do the other injectors pull out as well when you lift the fuel rail or can you isolate the one you want?
They do come up, but they are still attached to the fuel rail so they don't (shouldn't) release any gas. The injectors aren't under compression, so they are just held in the intake manifold by their o-rings and the fuel rail itself.
How difficult is this task?
Service manual puts it at 4.6hrs to replace the valve cover gasket. The valve seals are 2.7hrs plus the valve cover gasket time. The driver's side is pretty straightforward, the passenger side requires draining the cooling system if you have rear climate control because those hoses need to be disconnected.
It's a solid weekend job, but it can be done.
The valve seals are harder. You have to ensure the valves don't fall into the cylinder, and if they do, you get to remove a head, yay! It's pretty unlikely it's the valve seals, though. More likely the seals around the spark plug wells that you change along with the valve cover gaskets.