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for the rear defrost ck the connections at the window if they are ok test across the 2 with test light of volt meter to ck for voltage if the voltage is there then look for little openings in the lines across the window
that may be but testing for the power at the rear widow is the easiest if no power then I would ck the switch and any relays related to it. the fuses are 27 at battery fuse box and 6 in the fuse box at dash. ther is a relay at the battery fuse box called the heated grid relay also to ck.